I can't see where your first PCH_PATH is pointing as the column has not been extended. However, the second two paths are both wrong. Record 25 says the PCH is looking for TV Series but you have it pointing to a root folder on your A410 called Movies - which is obviously wrong. Row 27 is pointing to simply 'multimedia' but the windows path is pointintg to 1 level lower (multimedia\movies), that one you need to take the \movies off the end.
The windows path must ALWAYS point to the same location as the PCH path is looking at.
Remember, if you change path mapping you will need to re-add all of the files on that share. Simply run 'Remove Deleted File Entries' after changing the windows paths - this will remove all entries where they have an invalid path. Then re-scan your media. If you are not sure if you have set the paths correctly simply add one file from that share and then see if it plays. If it does not then you have still not corrected the path.