Well, you need appropriate speakers with two sets of terminals. There will be some sort of connection to be used when not bi-wiring or bi-amping. You don't want to connect two amp outputs together. Read the speaker manual.
You need a second set of cables. Read the cable manual (joke).
I don't know your Denon but I have the X3200W. On mine, the usual front outputs go to one set of terminals on the speakers. There is another set of outputs which have multiple uses: e.g. 7.1, Atmos, zone 2, or bi-amping. Finally, you tell the amp that you want this. Again, read the manual.
I tried it once just because I could. I had two channels doing nothing. Was it worth it? No, not for me anyway, I could not tell any difference. I was a bit disappointed that Audyssey did not calibrate the two channels independently. I was also surprised that it was not specified which outputs went to which speaker terminals.
Will i do it again? No, partly because I could not detect any benefit but also because I bought some Atmos speakers and I no longer have any spare outputs. This is a much better use of the extra outputs. 7.1 is also good but I prefer Atmos.