By the way, here is my current settings:
Picture Mode : Cinema (think this is just the name tbh)
Contrast: +26
Brightness: +6
Colour: -12
Sharpness: +5
Hue : +5
Colour Temperature: Cool
Backlight: +8 - 184 watts power consumption for those interested
Deep Colour: Off
Contrast Mode: Linear (seems to give a more even black level across the picture, instead of just too black on the black bits, or not black enough)
3D Colour Management: Off
Black Enhancement: Off
Digital Noise Reduction: Low (not a fan of NR but it makes a slight difference, also helps with a slight banding caused by my TUTV S-Video output - is fine on the Sky+)
MPEG NR: Low (as above)
Cross Colour NR: Low (as above)
Game Mode: Off
Film Mode: Smooth 2 (none of these settings seem to make any difference)
Colour Temps:
Amplitude
Red: -6
Green: 0
Blue: 0
Cut Off
Red: 0
Green: -8
Blue: -19
Have been tinkering for 20 mins or so after setting it to the settings posted by jojomuniandy, however my eyes are starting to get tired and I will have another look at it tomorrow.