Getting hold of either shouldn't be too much of a problem. I have a branch of TLC nearby and they stock both.
I found an off cut of PF100 at home which is just long enough for the two runs for the job intended (i.e. up a vertical run into the loft and adjacent to a power socket where the multiswitch will ultimately end up). I have managed to stuff that up the conduit and into the loft so the plasterer can start tomorrow.
I think I may have to use shotgun on the other rooms though. I am using this module:
Screened Quadplexed Module - Screwfix.com, Where the Trade Buys
with this faceplate:
Modular 4 Gang Faceplate - Screwfix.com, Where the Trade Buys
and a couple of these:
Cat5E Outlet Module - Screwfix.com, Where the Trade Buys
and bending the PF100 into the module was a complete pig as the gap between the bottom of the module (where the cables terminate) and the bottom of the standard UK back box is really tight.
Having looked at the shot gun cable available from TLC, it shows 2x 4.8mm cables welded together. I am assuming this weld will be like speaker cable and can be split (indeed this would be required at both the LNB and receiver anyway) and being 4.8mm instead of the 6.8mm of the cable I currently have, I hope it will bend easier.
Only thing will be signal quality. The cable is bent so tight at the moment, god only knows whether it will work, but I don't have anything connected to the other end to test it. Guess I will have to hope and pray it works!