Yep , if you're going to use rockwool / rocksil you will ned to create a cavity in which to put the rockwool!
Ring back sheffield insulations (nice people im up there all the time) and enquire about an MF frame system. Its easy to put up , you can put your rockwool inbetween and the fix the boards to the frame!
As for the prices they seem very reasonable considering the book privce for a soundbloc board is £17! Theyve given you a good reduction there!
Dont forget you're going to have to pay for a jointer to come in for a day to joint it (reakon on around £150 a day labour) and if you're not building it then you'll need someone to put up the mf frame section (reakon again on £150 a day for the labour)
MF...
You'll need some MF6A , its a 'c' shapped metal channel which runs down two sides of your room (the opposite way to your ceiling joists) oncve fixed in place you'll need some MF5's these slot inbetween the MF6A and run the length of the room at approx 400mm centres! Next put the rockwool between the MF5's and then you can board it , remembering to stagger the joints!
I wouldnt use rockwool / sil with the existing plasterboard and the new soundbloc on top this should give sufficient soundproofing and would mean you wouldnt need the MF frame section!
All in my opinion of course!
Feel free to pm me for any advice you may need
Jon