The resolution I'd expect to be the same. What is differeent is compression.
I have Freeview, not Sky, so can't give a fair comparison opinion.
But Freeview is supposed to have fewer channels so they can have a better compression ratio, and it's a fixed allocation. It's hard to tell if there's been any quality increase. The BBC channels always looked better than ITVDigitals extra channels.
Sky uses a variable compression allocation. My parents, and sisters have Sky Digital. It doesn't look any better. Well, worse if anything as they haven't really optomised any settings.