ATI cards were able to output a combined sync, however I do not know whether recent ATI/AMD cards can still do that. I know that nVidia cards have never been able to do it.
That is not a big problem because nVidia cards can be connected to RGB scart connectors but they need a small circuit to combine the separate H & V sync into a combined sync to feed the TV. Therefore the same could be used with ATI/AMD cards if they are no longer able to output combined sync's.
The biggest problem and the one which might prevent newer cards from working is that they tend to be limited in what pixel clocks they can use. They tend not to be able to use low enough pixel clocks to output the required resolution and refresh rates.
I had wanted to build a project box with a vga to scart and audio switching from my Pc but I don't want to be buying lots of parts if the graphics card won't work at such low clocks. My gfx card is a GT240 and nVidia support were not very helpful, they didn't seem to know whether it would work. They are American I believe and this is not something that is possible on US TV's which rarely have RGB connections and therefore they have no experience in doing it. It's a pity that their tech people couldn't answer whether the card is capable of the required low clock.
This is the site which suggests that my GT240 cannot use the required pixel clock.
I might have to make a quick mock up cable and see if it works before spending on the parts to make the full idea I have. The highest quality parts would make a difference when working in the Analogue world of RGB scart so I wouldn't want to scrimp when making the final product.
It's surprising that there are still people who want to do this and are still using CRT TV's. Thumbs up to norm's words on black levels on decent CRT's when compared to LCD's and that's before you even get onto the movement.