Are you running XP?
If so then you can mix CD/DVD-HDD on the same cable without slowing down to PIO v UDMA etc.
I wouldn't have your capture HDD on the same cable as your boot HDD. (I assue you have the second HDD set as slave etc)
My personal choice (through trial and error!) would be as follows.
Primary IDE:
Master = Boot HDD
Slave = DVD
Secondry IDE:
Master = Storage HDD
Slave = DVD Writer
Having the HDD on the same lead causes problems with windows swop file(or virtual memory) speed.
It's free to try, and if you don't like my setting swop them back!