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if you are using DV then green actually works better, green is sampled more in DV than blue, so the machine has more info to work with, avoid the selected colour being in your subject (although some programmes have garbage mattes to get round this) also some folk use a soft pink gel on the back light, as this helps to eliminate any spill from the background onto your subject. To do this right you do need to use at least 4 lights, ideally 5 (key, fill back on subject, even illumination on backdrop, either two lights or a single light with a softbox. Some shadows aren't a problem with most suites as you can change the latitude and tolerance of the chroma range up to a wide degree, however crease, folds or seams in your fabric can be a real pain as these often register as black, and as such won't be easily chroma's out.
If you have photoshop you can paint in chroma areas on some parts of the frame as long as your subject is quite static.
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