I've revisited some of these sites that I was looking at a few years ago.
LibraryThing- Ability to sort on author surname (seems obvious, but they don't all seem to do it unless I've just missed something).
- The concept of a "work", i.e. something at a higher level than book. Avoids having reviews in multiple places.
One thing that I find a bit irritating is that if you follow links to other books already registered on the site, you can't then add them directly to your collection. It forces you into the search function.
Shelfari
Just looked at this again and it seems to be better than I remembered. I don't like the "shelf" views, but the edit view is usable.
Listal
Annoying that you can't sort by author surname.
Bibliophil
I can't work out how to add books. Possibly by ISBN only.
Gurulib
I though it looked promising, but then saw that it wasn't sorting by author surname.
reader2
Looks better, less cluttered than some of the others but I'm not sure about the usability.